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There's quite a bit of research literature on the phytocompounds in onions and their scaly outer skins, David. 

This Overview  from the onion trade organization contains a lot of scholarly references at the end.Here's another reference to check out:

Antibacterial and antioxidant activities of quercetin oxidation products from yellow onion (Allium cepa) skin

In commercial food-processing operations, onion skins are often characterized as industrial waste. Of course, the processors would be eager to find profitable uses for them:

Characterization of industrial onion wastes (Allium cepa L.): dietary fibre and bioactive compounds.

 

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